Nafion and the perfluorinated benchmark (1962)
DuPont chemist Walther Grot produced Nafion, a perfluorosulfonic acid membrane that became the default proton exchange material in fuel cells for over six decades. Its high cost and fluorine chemistry drew criticism almost from the start.
Nafion powered research fuel cells and early vehicles, setting the performance baseline the industry still uses.
Decades of rivals (sulfonated polyaromatics, composites, graphene oxides) have not displaced it in commercial stacks.
The BIT membrane is the latest challenger to that standard; the pattern of prior challengers is that lab performance alone has never been enough to win the stack market.
