Antiferromagnetism and neutron diffraction (1930s–1949)
Louis Néel predicted antiferromagnetism in the 1930s, a magnetic order with no net magnetization that ordinary magnetic measurement could not see. Clifford Shull confirmed it in 1949 by scattering neutrons off the atomic spin arrangement in manganese oxide.
Neutron diffraction verified Néel's theory and gave researchers a way to see magnetic structure directly.
Shull shared the 1994 Nobel Prize in Physics, and neutron scattering became a standard tool for mapping magnetic order.
Antiferromagnetism was hidden to ordinary probes for decades until a new measurement technique appeared. Octupolar order sits in the same position today, with the rotating-light method proposed as its neutron-scattering moment.
